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2015-5-4 9:38 : Mashi () [ 13038hit ]

   Ųߤ򿨤äꡢסݥۡݥȤäꡢŴͷӤʤɡ°򴶤ȤϾʤʤȻפޤǤ⤳˶°ʤΤǤ礦̾ʪϡϤŪʬҤδȯͭʪǤΤʨι⤤°बȯ̾ϤƤȤϹͤˤǤǤ϶°ȤϰβʤΤǤ礦¤϶ǯʬޤ

   NatureΥ˥塼ǤҲ𤵤줿ΤǤɥĥ饤ץؤθबβĩߤޤŴFe2+ˤȿ͹δȤҥȤ˺Ѥȯ벽ʪ򥬥ޥȥեʬϤޤη̡Ŵ˿줿椫ϡʪȤúǿ710ľǥҥ1-ƥ-3-󤬸Фޤʿ޻ȡˡ°ˤϡʬȤƥޤǤΤ⤢ꡢξˤϥ󲽹ʪΥۥե󡢥ۥեʿ޻ȡˤȤäʬǤƤ뤳Ȥʬޤɡֶ°פȻפƤΤϡ°ΤΤǤϤʤ°ˤä餬ʬ򤵤ƤǤʪκ礷äΤǤ

   1-ƥ-3-ϡؼCH2=CHCO(CH2)4CH3ɽ˰¥ȥΰǡ
°ޥå롼཭սȤΤǻ٤ǤⴶʪǤ礭ǸʬޤǤϴ饹̤Τ褦˥饭鸫ޤĴ٤ʬϡ¤ϻ䥿ѥǤؤϥߥǸȡʤɤͭʪǥɥɥʤΤǤ
   °ϡ¤϶ϤʻޤǤλϤϡ䥤ƼŴ䰡䥢ߥ˥।ν֤Ǥ°ȯᥫ˥ϡޤ°ȴȿƶ° ۥλʬʤɤԤ1-ƥ-3-ʤɤδȯʪȯ뤳ȤʤΤǤβȿ϶ˤû֤ǵޤĤޤֶ°פ϶°ǤϤʤΤФʪפäΤǤ

   Τ򿩤٤Ȥζ°˴ؤ븦⤢ޤҥȤ°(Fe2+)οϱդ˴ޤ˴°ɤƤΤĴ٤Ȥˤ¦ǶŴ졢ݥƥݣݥ󤬸ФޤݥƥݣݥϡŴȻȿ櫓Ǥº¦Ǵ줫Фޤ˸Ŵϡ¦Ƭʤɽ̤Ǵʤ줿ȿƤ뤳Ȥʬޤ

   ȶʶ°¤ϼʬΤδ(α)Ȼ˸äȤ϶äǤǶޤ椬°϶°ȻפäƤQϰβäΤǤ礦(by Mashi)


ʸ1) Dietmar Glindemannet al., The Two Odors of Iron when Touched or Pickled: (Skin) Carbonyl Compounds and Organophosphines. Angew. Chem. Int. Ed., (2006) 45, 7006-7009. 2)ƣǷ顧ǴŴꡡ̵ͻVol.90, No.3, 41-502011
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